• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a method of manufacturing aluminum alloy ingot using 2xxx or 7xxx series aluminum alloy scrap in which (i) 2xxx or 7xxx series aluminum alloy scrap is supplied; (ii) optionally separating the oil present on the scrap, (iii) performing a first operation of treating said scrap with a first liquid at a temperature of at least 10 ° C., said first liquid being a solution 1 to 5 or 8 to 13, (iv) separating the first liquid and the scrap thus treated, (v) performing at least a second operation of treating said scrap with a second liquid, (vi) separating the second liquid and the scrap thus treated, (vii) melting said scrap thus obtained, (viii) pouring an ingot of aluminum alloy of the scrap series used. The ingots obtained by the process according to the invention can advantageously be used for the manufacture after rolling, spinning and / or forging of aeronautical structural elements.
    公开号:FR3023848A1
    申请号:FR1401590
    申请日:2014-07-16
    公开日:2016-01-22
    发明作者:Alireza Arbab；Laurent Boissonnet；Jules Diawara；Pascale Hervieu；Anne Pichat
    申请人:Constellium France SAS；
    IPC主号:
    专利说明:

    [0001] FIELD OF THE INVENTION The invention relates to the manufacture of aluminum alloy ingots of the 2xxx or 7xxx series from scrap (raw materials for recycling, such as chips or machining scrap) alloy of the corresponding series. The invention particularly relates to the recycling of scrap resulting from the manufacturing processes of the aerospace industry. STATE OF THE ART In several industries, processes for manufacturing finished metal products by processes such as machining, processing, cutting intermediate products generate significant amounts of chips and machining scrap. In the present text this waste is designated by the term "scrap" which is used in the standard EN 12258-3 entitled "Aluminum and aluminum alloys - Terms and definitions - Part 3: Scrap (raw materials for recycling)", to designate products for recycling (aluminum). The aeronautical and space industries generate in particular a large amount of scrap because many structural parts and components of an aircraft are obtained by integral machining of massive parts. However, scrap is often difficult to recycle directly because of mixing with other aluminum alloys or other materials used in aeronautics such as stainless steels and titanium (Wilson et al., Journal of Physics C-75 1987). For example, machining waste from aeronautical alloys is often recycled into aluminum-silicon alloys for molded products. This valuation path will be referred to in the remainder of the text as "usual channel". It leads to a partial loss of the value of the metal and moreover will soon not be able to absorb all of the scrap from the aerospace industry. 1 It is also possible to manufacture aluminum alloy products for aeronautical and space applications from scrap. The patents FR2801060 and FR2902800 thus describe the manufacture of alloy products and semi-finished products of the 2xxx series or of the 7xxx series from recycled raw materials such as chips or machining scrap. This recycling is made possible by a purification step of certain impurities. This valuation route will be referred to in the rest of the text as "aeronautical industry". The recycling problem of scrap is particularly sensitive for alloys 2xxx or 7xxx Al-Li type. The term "alloy 2xxx or 7xxx Al-Li type" means any alloy 2xxx or 7xxx containing an amount of lithium greater than 0.2% by weight and preferably greater than 0.5% by weight. The common point of these alloys is the need for special precautions related to the oxidability of lithium. Aluminum alloys containing lithium have a lower density than traditional aluminum alloys and are therefore very promising to reduce the weight of aeronautical parts. However, 2xxx or 7xxx alloys of Al-Li type are significantly more expensive than non-lithium alloy products, for three reasons: the intrinsic cost of lithium, the cost of making the metal in a foundry, and the difficulty recycling scrap.
    [0002] Indeed, it is known that the recycling of Al-Li type alloy scrap in the "aeronautical industry" is difficult (Wilson et al., Journal de Physique C-75 1987). The international application WO2007 / 015013 teaches a process for melting scrap aluminum alloy containing lithium in which in particular the scrap is loaded on an initial bed of liquid metal so as to create on the surface of the liquid metal bed a floating mattress controlled thickness that minimizes the use of expensive consumables such as inert gas. It has been found that the known processes do not always make it possible to recycle the ingots obtained by reflow in the "aeronautical industry", in particular because of the increase in the content of certain alkaline elements such as sodium or alkaline earth such as calcium or even some metals like iron. It is known to those skilled in the art to remove alkali or alkaline earth elements when casting aluminum by a chlorination process in a suitable pocket. 2 However, it is particularly advantageous because of the constraints related to the use of chlorine for safety and environment not to use this gas in the foundry and moreover in the case of alloys 2xxx or 7xxx Al-Li type this process has disadvantage of also eliminating a large part of the lithium and thus not being economically advantageous. The problem that the present invention seeks to solve is therefore to propose a new approach for manufacturing aluminum alloy ingots of the 2xxx or 7xxx series that makes it possible to incorporate a significant fraction of finely divided scrap while obtaining a low content of impurities. such as alkaline elements such as sodium, alkaline earth elements such as calcium or certain metals such as iron. OBJECT OF THE INVENTION A first object of the invention is an aluminum alloy ingot manufacturing method using aluminum alloy scrap of the 2xxx or 7xxx series in which (i) alloy scrap is supplied. aluminum of the 2xxx or 7xxx series; (ii) optionally separating the oil present on the scrap, (iii) performing a first operation of treating said scrap with a first liquid at a temperature of at least 10 ° C., said first liquid being a solution 1 to 5 or 8 to 13, (iv) separating the first liquid and the scrap thus treated, (v) performing at least a second operation of treating said scrap with a second liquid, (vi) separating the second liquid and the scrap thus treated, (vii) melting said scrap thus obtained, (viii) pouring an ingot of aluminum alloy of the scrap series used. Another object of the invention is the use of an ingot of aluminum alloy 2xxx or 7xxx obtained by the process according to the invention for the manufacture after rolling, spinning and / or forging selected aeronautical structural elements. Among the elements that make up the fuselage, such as fuselage skin, stiffeners or fuselage rails, bulkheads, fuselage frames, wings, such as wing skin, stiffeners, ribs and spars, and tail fin consisting in particular of horizontal and vertical stabilizers, as well as the floor profiles, the rails of seats and the doors.
    [0003] Description of the Figures Figure 1: Diagram of a scrap treatment line according to the invention. DESCRIPTION OF THE INVENTION Unless otherwise indicated, all the indications relating to the chemical composition of the alloys are expressed in percent by weight. Therefore, in a mathematical expression, "0.4 Li" means: 0.4 times the lithium content, expressed as a mass percent; this applies mutatis mutandis to other chemical elements. The designation of the alloys follows the rules of The Aluminum Association, known to those skilled in the art. Unless otherwise stated, the definitions of the European standard EN 12258-1 apply. Terms related to scrap and recycling are described in EN12258-3. The term "machining" includes any material removal process such as turning, milling, drilling, reaming, tapping, EDM, grinding, polishing. The scrap capable of being recycled by the method according to the present invention may be in various forms, but preferably comprises finely divided scrap, ie scrap consisting of elements whose cross section is less than 50 mm 2. One of the particularly preferred forms is referenced under the term "turnings" in the EN12258-3 standard, which refers to the production scrap 4 composed of grains, chips, curls, produced by machining or other operations. The scrap that can be recycled in the context of the invention can be in different states: mainly loose scrap and ground scrap, the scrap granules may be suitable in cases where the component parts are of a sufficiently small size. The dimensional characteristics of the scrap are important for the realization of the present invention. If the scrap is supplied in compacted form, a decompacting step is most often necessary. The scrap used in the context of the present invention is also characterized by its density. The apparent density of the scrap is measured as follows: a cylindrical container with a capacity of 1 liter is filled with scrap, a vibration is produced in the form of small shocks so as to pack the scrap. The operation is repeated until the container is filled to the brim. The weight of the filled container from which the weight of the empty container is subtracted makes it possible to determine the apparent density of the scrap. It is preferable that the apparent density of the scrap is between 0.05 and 0.8 t / m3 (ton per cubic meter), preferably 0.1 to 0.7 t / m3 and even more advantageously between 0, 2 to 0.4 t / m3. The present inventors have found that the chemical composition of the ingots obtained after melting the scrap can be significantly improved when the scrap undergoes a first treatment operation with a first liquid at a temperature of at least 10 ° C., said first liquid being a solution acidic or basic aqueous, pH 1 to 5 or 8 to 13 respectively, followed by at least a second treatment operation with a second liquid. Advantageously, the first liquid is acidic, and its pH is between 1 and 5, preferably between 2 and 4 and preferably between 2 and 3. Mineral acids, such as in particular phosphoric acid, sulfuric acid or nitric acid or organic acids such as in particular acetic acid, citric acid, sulfamic acid, may be used alone or in combination so as to obtain the desired acidic aqueous solution. Preferably the first liquid contains phosphoric acid. Treatment with a first acidic liquid is more effective for the removal of undesirable impurities than treatment with a first basic liquid. In the case of a first basic liquid, it is possible to use organic bases, products based on ammonia and / or mineral bases, in particular alkaline salts such as sodium hydroxide or potassium hydroxide, and alkaline earths such as lime. are typically used. Salts containing silicates are advantageous. The treatment temperature of the first liquid is advantageously between 20 and 80 ° C. In general, the scrap is coated with lubricants which may be emulsions or whole oils and which are generalized here by the term "oil". The amount of oil present on the scrap varies depending on the manufacturing step at which it is generated and the technology used to remove the metal. Thus the amount of oil present on the scrap obtained during the scalping operation of the rolling plates is generally low. On the other hand, the amount of oil on the scrap from machining operations is much higher. The present inventors have found that a degreasing of the scrap with the aid of a detergent alone, that is to say a product comprising at least one chemical compound with surfactant properties also called surfactant or surfactant, does not allow to significantly reduce the content of undesirable impurities after recycling. A prior step of separating the oil, typically by dewatering or centrifugation or by treatment with an organic solvent or a neutral pH detergent before the first treatment operation with the first aqueous or basic aqueous solution, may, however, be advantageous for avoid too much oil pollution of the first liquid during the first treatment operation. Advantageously, the first liquid comprises at least one surfactant product. Preferably, the surfactant product is a nonionic surfactant product because these products can further reduce the content of undesirable impurities. Among the suitable nonionic surfactant products are the ester-linked products R-CO-O-R ', where R is a non-polar chain and R' is a polar chain, such as glycol esters, for example ethylene glycol stearate, glycerol esters, for example glycerol stearate, polyoxyethylene glycol esters, sorbitan esters, and polyoxyethylene sorbitan esters, more commonly known as Tweens or polysorbates, sugar esters, surfactants wherein R is a non-polar chain and R 'is a polar chain, such as ethers of polyoxyethylene glycol fatty alcohols, for example TritonX100 of the formula C8F117C6H4 (OC2H4) 9 -10 OH); the amide bonded surfactants R-CO-NH-R ', where R is a non-polar chain and R' is a polar chain. The duration of the first treatment operation depends on the mixing conditions and the ratio between the amount of treated scrap and treatment solution. Typically the treatment time is between a few minutes and a few tens of minutes. The first operation can be carried out batchwise, batchwise or continuously. Advantageously, said first operation is performed by feeding the scrap continuously.
    [0004] Advantageously, during said first processing operation, a simultaneous treatment with ultrasound is carried out at a frequency typically between 10 kHz and 100 kHz and preferably between 15 kHz and 35 kHz. After said first treatment operation the scrap thus treated is separated from said first liquid, advantageously so that the residual amount of liquid does not exceed 50% by weight, preferably 20% by weight and preferably 10% by weight of the material transferred from the first operation to the second operation. The transferred material consists of the transferred scrap and the trapped liquid. Said separation may be carried out by means such as, for example, decantation, filtration, dewatering, centrifugation. Advantageously, said separation is carried out by centrifugation so that the residual amount of liquid does not exceed 10% by weight of the material transferred from the first operation to the second operation. The thus separated scrap then undergoes a second treatment operation with a second liquid.
    [0005] In one embodiment of the invention, said second treatment step is a rinse and said second liquid essentially comprises water, preferably the second liquid in this embodiment is deionized water. In another embodiment of the invention said second liquid is an aqueous solution whose pH is greater than the pH of the first liquid, if the first liquid has a pH of between 1 and 5 and less than the pH of the first liquid if the first liquid has a pH between 8 and 13, preferably the pH of the second liquid 7 being between the pH of the first liquid and 7. In all cases it is advantageous to add in said second liquid at least one surfactant, preferably a nonionic surfactant of the type of those described as possible additives to the first liquid.
    [0006] Advantageously, during said second processing operation, a simultaneous treatment with ultrasound is carried out at a frequency typically between 10 kHz and 100 kHz and preferably between 15 and 35 kHz. Other processing steps by other liquids may be added between said first processing operation and said second processing operation or after said second processing operation. Between each treatment step, the treated liquid treatment scrap is separated, preferably so that the residual amount of liquid does not exceed 50% by weight, preferably 20% by weight and preferably 10% by weight of the product. the transferred material, advantageously by centrifugation. Advantageously, the method comprises only the first and the second processing operation. After the last treatment operation with a last liquid, the last treatment liquid and the scrap are separated, advantageously so that the residual amount of liquid does not exceed 3% by weight, preferably by centrifugation, and / or when it is dried. scrap by heat treatment in an oven at a temperature typically between 105 and 130 ° C. Advantageously, centrifugation and drying are carried out. Preferably, the processing operations of the scrap are carried out continuously and the treatment liquids flow in opposite flow to that of the scrap. Advantageously, said second liquid feeds said first liquid preferably with a volume flow rate of at least 0.1 times the volume flow rate of the scrap and preferably between 0.2 and 1 time, preferably 0.3 and 0.8. the volume flow rate of the scrap feedstock and the quantity of the first liquid entrained does not exceed 50% by weight, preferably 20% by weight and preferably 10% by weight of the transferred material, typically by centrifugation after the first treatment operation. FIG. 1 illustrates a continuous embodiment of the method according to the invention. The scrap flow is represented by the double arrows (1) and the liquid flow is represented by the single arrows (2, 21). The flow of liquid is opposed to the flow of scrap. The scrap is supplied and undergoes an oil separation step in a suitable device (60). The scrap then undergoes the first treatment operation with the first liquid in the device (31), a separation of the first liquid in the device (41), the second treatment operation with the second liquid in the device (32), a separation second liquid in the device (42), and is then dried and remelted. The first liquid is stored and optionally reprocessed and / or stabilized in the first tank (51) which supplies the device (31). The second liquid is stored and optionally reprocessed in the second tank (52) which supplies the device (32). The second liquid feeds the first liquid (21). The scrap capable of being recycled in the context of the present invention consists essentially of alloys of the 2xxx series or the 7xxx series, these alloys not typically having to be mixed. Among the alloys of the 2xxx or 7xxx series containing no lithium, suitable alloys are, for example, the alloys AA2X24, AA2026, AA2027, AA2029, AA2139, AA2056, AA7010, AA7X40, AA7X49, AA7X50, AA7X55, AA7X75, alloys. AA7X81, AA7X85. Advantageously, the scrap capable of being recycled in the context of the present invention consists essentially of alloys 2xxx Al-Li suitably sorted. Suitable alloys are, for example, AA2050, AA2055, AA2060, AA2065, AA2070, AA2076, AA2090, AA2091, AA2094, AA2095, AA2097, AA2098, AA2099, AA2195, AA2196, AA2197, AA2198, AA2199, AA2295, AA2296, AA2297 alloys. , AA2397, as defined by the Aluminum Association. The present invention makes it possible to produce ingots that can be used in the aerospace industry in these alloys from scrap.
    [0007] The method according to the invention may also comprise a step intended to reduce the amount of massive ferrous waste, in particular a magnetic sorting system making it possible to eliminate ferrous elements such as screws or bolts which may have contaminated the scrap. The dried scrap is then melted. A melting method as described in WO2007 / 015013 in which the scrap is loaded onto an initial bed of liquid metal so as to create a floating mat of controlled thickness on the surface of the liquid metal bed is advantageous. In another embodiment of the invention, the scrap is introduced into an oven in which a swirling motion is created so as to achieve rapid immersion. In an advantageous embodiment of the invention the scrap resulting from the treatment with the first and the second liquid is compacted to be introduced into a melting furnace from which is poured a directly usable ingot for rolling, forging and / or spinning. The thus melted scrap is finally cast in the form of an alloy ingot of the scrap series used, that is to say of the 2xxx series if the scrap used is of the 2xxx series and the 7xxx series if the scrap used is from the 7xxx series. The ingot may be cast directly or after a first solidification in an intermediate form not usable for subsequent deformation such as a "bowl" or a "sow". Advantageously, the metal portion of the ingot resulting from the melting of the scrap is at least 5% by weight, preferably at least 15% by weight and preferably at least 25% by weight. The rest comes from other aluminum-based products and alloying elements added to correct the title of the metal. Said other aluminum-based products are typically, on the one hand, large size recycled products, such as 2xxx or 7xxx series alloy scrap, the composition of which is known, and on the other hand aluminum products. said "new", that is to say in so-called "pure" aluminum or low alloy typically containing more than 99.8% of aluminum.The ingot thus obtained can be used in the aeronautical industry. be a rolling plate, which after rolling will typically be transformed into thin sheet or thick sheet metal, or a spinning billet which after extrusion will be transformed into a profile or a forging blank which after forging will be transformed into forged product, these sheets, profiles and forged products that can be used for the manufacture of aeronautical structural elements such as the elements that make up the fuselage (such as the skin fuselage skin, the stiffeners or stringers, bulkheads, circumferential frames, wings (such as wing skin), stiffeners (stiffeners), ribs ( ribs) and spars) and the empennage composed in particular of horizontal and vertical stabilizers (horizontal or vertical stabilizers), as well as the floor beams, the seat tracks and the doors.
    [0008] EXAMPLES EXAMPLE 1 In this example, different solutions have been investigated for treating 2x Al-Li alloy 2xxx scrap. Scrap from AA2050 alloy machining was supplied. The composition measured after melting is given in Table 1 Table 1. Composition of the scrap (% by weight for Cu, Li, Mg, Ag or ppm for Ca and Na) Cu Li Mg Ag Ca Na 3.5 0.8 0.3 0.4 51 18 500 g of scrap was treated for 10 minutes with 4 liters of a first liquid whose composition is given in Table 2, rinsed with deionized water and then dried in an oven at 105 ° C for about 3 hours. Table 2. Treatment conditions pH treatment Tensio-active temperature Main component - concentration 1 11.7 50 ° C Fatty alcohol C13-15 ethoxylated Tetrasodium pyrophosphate and anhydrous disodium tetraborate (15g / 1) 2 7 50 ° C C8H17C6H4 (0C21-14) 9- 100E1 (1g / 1) 3 2 16 ° C Nitric acid (1g / 1) 4 3 16 ° C Acetic acid (20g / 1) The scrap was then melted and poured. The composition obtained is given in Table 3. TABLE 3 Composition of the scrap obtained after treatment and melting (% by weight for Cu, Li, Mg, Ag or ppm for Ca and Na) Treatment Cu Li Mg Ag Ca Na 1 3.3 0.8 0.3 0.4 25 17 2 3.4 0.7 0.3 0.4 49 10 3 3.6 0.8 0.3 0.4 27 10 4 3.6 0.8 0.4 0.3 25 8 Treatments 1, 3 and 3 4 according to the invention allow to obtain a composition after casting used in an alloy ingot AA2050, the calcium content being 50% lower than that of the initial scrap. Treatments 3 and 4 are particularly advantageous because the sodium content is also low.
    [0009] Example 2: In this example, other liquids were studied to treat another batch of alloy 2xxx Al-Li alloy scrap whose composition is given in Table 4.
    [0010] Table 4. Composition of scrap (% by weight for Cu, Li, Mg, Ag or ppm for Ca and Na) * Cu Li Mg Ag Ca Na 3.6 0.8 0.3 0.4 45 130 * Ca and Na content is measured surface and the content present in the metal is added 500 g scrap was treated for 30 minutes in 4 liters of a liquid whose composition is given in Table 5, rinsed with deionized water and then dried in an oven at 105 ° C for about 3 hours. Table 5. Treatment conditions pH treatment Tensio-active temperature Main component - concentration 2 20 ° C C81-117C6H4 (0C2H4) 9- 100H (1g / 1) H3PO4 (5 g / 1) 6 2.2 20 ° C H3PO4 (1 g / 1) 1) 7 1 20 ° C HNO 3 (5 g / l) 8 2.6 20 ° C CH 3 COOH (20 g / l) 9 7 50 ° C C 8 H 17 C 6 H 4 (OC 2 11 4) 9-100H (1 g / l) 10 -7 50 ° The amount of calcium remaining in the scrap after the treatment was calculated by adding the amount present in the metal and the extractable amount. . The results are given in Table 6. Table 6. Composition of the scrap after treatment, (% by weight for Cu, Li, Mg, Ag or ppm for Ca and Na) * Treatment Cu Li Mg Ag Ca Na 5 3.6 0.8 0.4 0.4 20 2 6 3 , 6 0.8 0.4 0.4 23 15 7 3.6 0.8 0.3 0.4 21 12 8 3.6 0.8 0.4 0.4 23 2 9 3.6 0.8 0.4 0.4 38 42 3.6 0.8 0.4 0.4 40 42 11 3.6 0.8 0.3 0.4 46 42 10 * the Ca and Na content is measured in surface area and the content present in the metal is added. Treatments 5 to 8 according to the invention make it possible to obtain a composition after casting which can be used in an alloy made of AA2050 alloy because the content of Ca and Na is at least 50% lower than that of the initial scrap, the treatment being particularly advantageous. EXAMPLE 3 In this example, Al-Li type 2xxx alloy scrap was processed continuously, the composition of which is given in Table 7. The residence time of the scrap in the first and second liquids was about 5 minutes.
    [0011] Table 7. Composition of scrap (% by weight for Cu, Li, Mg, Ag or ppm for Ca and Na) * Cu Li Mg Ag Ca Na 3.6 0.8 0.3 0.4 85 63 * Ca and Na content is measured on the surface and the content present in the metal is added The scrap batch was treated with a first liquid whose composition is given in Table 8, centrifuged, rinsed with deionized water and centrifuged again. Table 8. Treatment conditions pH Tensio-active temperature Main component-concentration 2-2.5 50 ° C C81-117C6H4 (0C2H4) 9-100H (1g / 1) H3PO4 (5 g / 1) Table 9 gives for various treatment conditions the calcium content of the scrap. Table 9. Effect of treatment parameters on the composition of the scrap Treatment separation of the liquid after the first treatment operation% by weight ratio between Ca (ppm) * liquid in the volume flow rate transferred from the first supply to the first second liquid by operation (% by second liquid weight) and volume flow of scrap 12 Centrifugation 7% 0.5 22 13 Centrifugation 7% 0.25 25 14 Centrifugation 7% 0.1 73 15 Centrifugation 7% 1 21 16 Drainage 74 % 0.5 28 17 Drain 74% 0.25 74 * The Ca and Na content is measured at the surface and the content present in the metal is added.
    [0012] Test 12 makes it possible to reach a particularly advantageous compromise between the calcium content and the liquid consumption. 15
    权利要求:
    Claims (5)
    [0001]
    REVENDICATIONS1. A method of manufacturing aluminum alloy ingot using 2xxx or 7xxx series aluminum alloy scrap wherein (i) supplying 2xxx or 7xxx series aluminum alloy scrap; (ii) optionally separating the oil present on the scrap, (iii) performing a first operation of treating said scrap with a first liquid at a temperature of at least 10 ° C., said first liquid being a solution 1 to 5 or 8 to 13, (iv) separating the first liquid and the scrap thus treated, (v) performing at least a second operation of treating said scrap with a second liquid, (vi) separating the second liquid and the scrap thus treated, (vii) melting said scrap thus obtained, (viii) pouring an ingot of aluminum alloy of the scrap series used. 20
    [0002]
    The method of claim 1, wherein the pH of said first liquid is between 2 and 4.
    [0003]
    3. A process according to claim 1 or claim 2 wherein said first liquid contains phosphoric acid.
    [0004]
    The method of any one of claims 1 to 3, wherein said first liquid comprises at least one nonionic surfactant product. 30
    [0005]
    The process according to claim 4 wherein said nonionic surfactant product is selected from an ester linked product, an ether bonded product and / or an amide bonded product. 16. Method according to any one of claims 1 to 5 wherein a treatment with ultrasound at a frequency typically between 10 kHz and 100 kHz and preferably between 15 kHz and 35 kHz is performed during said first treatment operation and / or during said second processing operation. 7. Process according to any one of Claims 1 to 6, in which, after the last operation of treating said scrap with a last liquid, the last treatment liquid and the scrap are separated so that the residual quantity of liquid does not exceed 3% by weight and / or drying the scrap by heat treatment in an oven at a temperature typically between 105 and 130 ° C. 8. A process according to any one of claims 1 to 7 wherein said second liquid essentially comprises water, preferably the second liquid is deionized water, 9. A process according to any one of claims 1 to 7 wherein the second liquid is an aqueous solution whose pH is (i) greater than the pH of the first liquid, if the first liquid has a pH of between 1 and 5, or (ii) less than the pH of the first liquid, if the first liquid has a pH of between 8 and 13, advantageously the pH of the second liquid being between the pH of the first liquid and 7. 10. The method according to any one of claims 1 to 9 wherein at least one surfactant, preferably a nonionic surfactant is added in the second liquid. 11. Method according to any one of claims 1 to 10 wherein the scrap processing operations are carried out continuously and the treatment liquids flow in opposite flow to that of the scrap. 17. The method of claim 11 wherein said second liquid feeds said first liquid with a volume flow rate of at least 0.1 times the feed rate of the scrap and preferably between 0.2 and 1 times, preferably 0.3 and 0.8 times the feed rate of the scrap and in which the quantity of first liquid entrained does not exceed 50% by weight, preferably 20% by weight and preferably 10% by weight of the material transferred between the first and the second processing operation. 13. Method according to any one of claims 1 to 12 wherein said scrap is alloy 2xxx Al-Li type preferably selected from at least one of AA2050, AA2055, AA2060, AA2065, AA2070, AA2076, AA2090, AA2091, AA2094, AA2095, AA2097, AA2098, AA2099, AA2195, AA2196, AA2197, AA2198, AA2199, AA2295, AA2296, AA2297, AA2397. 14. Process according to any one of Claims 1 to 13, in which the metal portion of the ingot resulting from the melting of the scrap is at least 5% by weight, preferably at least 15% by weight and, preferably, at least 15% by weight. less than 25% by weight. 15. Method according to any one of claims 1 to 14 wherein the scrap from the treatment with the first and the second liquid is compacted to be introduced into a melting furnace from which is cast a ingot directly usable for rolling, forging and / or spinning. 16. Use of an ingot of aluminum alloy 2xxx or 7xxx obtained by the process according to any one of claims 1 to 15 for the manufacture after rolling, spinning and / or forging of aeronautical structural elements selected from the elements that make up the fuselage, such as the fuselage skin, the stiffeners or fuselage rails, the bulkheads, the fuselage frames, the wings, such as the wing skin, the stiffeners, the ribs 18 and longitudinal members and the empennage made up in particular of horizontal and vertical stabilizers, as well as floor profiles, seat rails and doors. 19
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    同族专利:
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    FR3023848B1|2018-04-20|
    US20170166997A1|2017-06-15|
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    优先权:
    申请号 | 申请日 | 专利标题
    FR1401590A|FR3023848B1|2014-07-16|2014-07-16|PROCESS FOR RECYCLING SCRAP OF 2XXX OR 7XXX SERIES ALLOYS|
    FR1401590|2014-07-16|FR1401590A| FR3023848B1|2014-07-16|2014-07-16|PROCESS FOR RECYCLING SCRAP OF 2XXX OR 7XXX SERIES ALLOYS|
    US15/325,711| US10876188B2|2014-07-16|2015-07-10|Method for recycling scrap of 2xxx or 7xxx series alloy|
    PCT/FR2015/051926| WO2016009139A2|2014-07-16|2015-07-10|Method for recycling scrap of 2xxx or 7xxx series alloys|
    CA2952306A| CA2952306A1|2014-07-16|2015-07-10|Method for recycling scrap of 2xxx or 7xxx series alloys|
    JP2017502266A| JP2017526814A|2014-07-16|2015-07-10|Recycling method of scrap of 2XXX series or 7XXX series alloy|
    KR1020177002318A| KR20170028374A|2014-07-16|2015-07-10|Method for recycling scrap of 2xxx or 7xxx series alloys|
    EP15756963.3A| EP3169819B1|2014-07-16|2015-07-10|Method for recycling scrap of 2xxx or 7xxx series alloys|
    CN201580037945.3A| CN106536768B|2014-07-16|2015-07-10|The method for recycling 2xxx or 7xxx series alloy waste material|
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